Scorpions kill and eats spiders and it is not surprising that the roles are reversed sometimes. But there haven't been many reports of tarantulas preying on scorpions. Rami Khashab recently published an observation of a Middle East Black Tarantula, Chaetopelma olivaceum (C. L. Koch, 1841) preying on a small Aegaeobuthus nigrocinctus (Ehrenberg, 1828) (Buthidae) in Lebanon.
The spider didn't seem to have been stung by the scorpion, who probably was killed instantly by the larger spider's chelicerae.
Abstract:
I report the first documented case of the buthid scorpion Aegaeobuthus nigrocinctus (Ehrenberg, 1828) serving as prey for the tarantula Chaetopelma olivaceum (C. L. Koch, 1841) in Lebanon. The observation was made during a nocturnal survey in the Mount Lebanon region. The case contributes to the limited records of tarantula predation on scorpions and underscores the role of prey-predator size asymmetry in facilitating high-risk predation among arachnids.
Reference:
Khashab R. Predation of Aegaeobuthus nigrocinctus (Ehrenberg, 1828) (Scorpiones: Buthidae) by a Middle East Black Tarantula, Chaetopelma olivaceum (C. L. Koch, 1841) (Araneae: Theraphosidae) in Lebanon. Euscorpius. 2025(423):1–3. [Open Access]